全文获取类型
收费全文 | 254篇 |
免费 | 9篇 |
国内免费 | 3篇 |
专业分类
化学 | 155篇 |
晶体学 | 2篇 |
力学 | 28篇 |
数学 | 29篇 |
物理学 | 52篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 18篇 |
2019年 | 14篇 |
2018年 | 22篇 |
2017年 | 9篇 |
2016年 | 24篇 |
2015年 | 7篇 |
2014年 | 19篇 |
2013年 | 23篇 |
2012年 | 27篇 |
2011年 | 24篇 |
2010年 | 11篇 |
2009年 | 9篇 |
2008年 | 3篇 |
2007年 | 12篇 |
2006年 | 2篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2003年 | 8篇 |
2002年 | 3篇 |
2001年 | 2篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1995年 | 1篇 |
1992年 | 1篇 |
1985年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有266条查询结果,搜索用时 15 毫秒
21.
Visible‐light‐driven photocatalytic degradation of fenpyroximate in rotating packed bed reactor using Fe3O4@PbS@Ni2P magnetic nanocomposite photocatalyst: Response surface modelling and optimization 下载免费PDF全文
22.
Marino Grozdek Rahmatollah Khodabandeh Per Lundqvist 《Experimental Thermal and Fluid Science》2009,33(2):357-370
Pressure drop behaviour of ice slurry based on ethanol–water mixture in circular horizontal tubes has been experimentally investigated. The secondary fluid was prepared by mixing ethyl alcohol and water to obtain initial alcohol concentration of 10.3% (initial freezing temperature ?4.4 °C). The pressure drop tests were conducted to cover laminar and slightly turbulent flow with ice mass fraction varying from 0% to 30% depending on test conditions. Results from flow tests reveal much higher pressure drop for higher ice concentrations and higher velocities in comparison to the single phase flow. However for ice concentrations of 15% and higher, certain velocity exists at which ice slurry pressure drop is same or even lower than for single phase flow. It seems that higher ice concentration delay flow pattern transition moment (from laminar to turbulent) toward higher velocities. In addition experimental results for pressure drop were compared to the analytical results, based on Poiseulle and Buckingham–Reiner models for laminar flow, Blasius, Darby and Melson, Dodge and Metzner, Steffe and Tomita for turbulent region and general correlation of Kitanovski which is valid for both flow regimes. For laminar flow and low buoyancy numbers Buckingham–Reiner method gives good agreement with experimental results while for turbulent flow best fit is provided with Dodge–Metzner and Tomita methods.Furthermore, for transport purposes it has been shown that ice mass fraction of 20% offers best ratio of ice slurry transport capability and required pumping power. 相似文献
23.
The oxidative coupling reaction between hydroquinone or catechols and various sodium benzenesulfinates was investigated using the laccase from Trametes versicolor, in the presence of O2 in a phosphate buffer solution at room temperature to afford sulfonyl benzenediols in 75–95% yield. 相似文献
24.
A reversed-phase dispersive liquid-liquid microextraction (RP-DLLME) method was developed for the preconcentration and direct HPLC determination of oleuropein in olive's processing wastewater (OPW) and olive leaves extracts. In conventional DLLME, the sedimented phase is a micro-drop of a chlorinated organic solvent that is not compatible with RP-HPLC. Therefore, solvent evaporation and reconstitution with an appropriate solvent is often required. In RP-DLLME, this problem was overcome by overturning the solvent polarity in the ordinary DLLME and replacing the organic solvent with water. A central composite chemometrics design was used for multivariate optimization of the effects of five different parameters influencing the extraction efficiency of the method. In the optimized conditions, a mixture of 1.4 mL of an ethyl acetate extract of sample and 40 μL water (pH 5.0) was rapidly injected into 5.3 mL of cyclohexane. After centrifugation of the formed cloudy mixture, a micro-drop of the aqueous phase was sedimented at the conical bottom of the centrifuge tube. This phase, that contained the preconcentrated and partially purified analyte, was directly injected into an RP-HPLC column for analysis. A mean extraction recovery of 102.5 (±4.5) % with enrichment factors exceeding 38, was obtained for five replicated analysis. The detection limit of the method (3σ) for OE was 0.02 μg L−1 for OPW and 2 × 10−3 mg kg−1 for olive leaves samples. The results showed that, RP-DLLME is a promising technique which is quick, easily operated and can be directly coupled to HPLC. 相似文献
25.
S. Shahidi A. Rashidi M. Ghoranneviss A. Anvari M. K. Rahimi M. Bameni Moghaddam J. Wiener 《Cellulose (London, England)》2010,17(3):627-634
In this work, the silver particle absorption and antibacterial activity of cotton fabric when modified by low temperature
plasma were investigated. The modification consisted of plasma pre-functionalization followed by one-step wet treatment with
silver nitrate solution. Oxygen and nitrogen were used as the working gases in the system, and the results were compared.
The results showed that nitrogen plasma-treated samples can absorb more silver particles than oxygen-treated samples, and
thus the antibacterial activity of the samples in this case, which was analyzed by the counting bacteria test, was increased
considerably. 相似文献
26.
The production of acoustic wave is one of the most important factors on the action of High Repetition Rate TEA-CO2 lasers. In this paper a three-dimensional mathematical modeling has been considered for investigation of temporal and spatial variations of acoustic waves in the laser cavity and its effect on the output of HRR lasers. By calculation of equations obtained from this model and plotting the pressure spectrum in different states, the effect of electrodes dimensions, cavity dimensions, gas flow velocity and repetition rate of laser in different times have been acquired. At last, optimum conditions for performance of laser action and having a good output have been arrived. 相似文献
27.
In this work, the effect of an axial external moveable magnetic field on the output power of a CuBr laser with small-bore tube has been investigated. In all experiments, by applying an EMF along the tube axis, the laser output power has been decreased and by moving the EMF toward the cathode region, more substantial decrease of output power has been observed. The effect is more significant at a magnetic field intensity of 1100 G, Ne gas pressure of 35 Torr, frequency of 19 kHz and voltage of 3.8 kV, such that there was no laser emission when the EMF was placed around the cathode. 相似文献
28.
29.
The catalytic activity of ortho‐palladated [Pd{C6H2(CH2CH2NH2)‐(OMe)2,3,4}(m‐Br)]2, a complex of homoveratrylamine in the copper‐free Sonogashira coupling reaction has been investigated. This complex is a catalyst that is efficient, stable and non‐sensitive to air and moisture in the Sonogashira reaction. In this homogeneous catalytic system, various aryl halides were efficiently coupled with phenylacetylene in mostly moderate to good yields in N‐methylpyrrolidone at 100 °C under copper‐free conditions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
30.
S. Kimiagar M. Sadegh Movahed S. Khorram M. Reza Rahimi Tabar 《Journal of statistical physics》2011,143(1):148-167
Using the Markovian method, we study the stochastic nature of electrical discharge current fluctuations in the Helium plasma.
Sinusoidal trends are extracted from the data set by the Fourier-Detrended Fluctuation analysis and consequently cleaned data
is retrieved. We determine the Markov time scale of the detrended data set by using likelihood analysis. We also estimate
the Kramers-Moyal’s coefficients of the discharge current fluctuations and derive the corresponding Fokker-Planck equation.
In addition, the obtained Langevin equation enables us to reconstruct discharge time series with similar statistical properties
compared with the observed in the experiment. We also provide an exact decomposition of temporal correlation function by using
Kramers-Moyal’s coefficients. We show that for the stationary time series, the two point temporal correlation function has
an exponential decaying behavior with a characteristic correlation time scale. Our results confirm that, there is no definite
relation between correlation and Markov time scales. However both of them behave as monotonic increasing function of discharge
current intensity. Finally to complete our analysis, the multifractal behavior of reconstructed time series using its Keramers-Moyal’s
coefficients and original data set are investigated. Extended self similarity analysis demonstrates that fluctuations in our
experimental setup deviates from Kolmogorov (K41) theory for fully developed turbulence regime. 相似文献